Search results for " interfacial interaction"
showing 3 items of 3 documents
PMMA-titania nanocomposites: Properties and thermal degradation behavior
2012
Titania nanoparticles were prepared using a solegel method and calcination at 200 and 600 � C in order to obtain anatase and rutile phases, respectively. The obtained powders were used to prepare PMMAe titania nanocomposites by a melt compounding method. The effect of the crystalline phase and the amount of titania, in the range 1e5 wt.%, on the morphology, mechanical properties and thermal degradation kinetics of PMMA was investigated by means of X-ray diffractometry (XRD), transmission electron microscopy (TEM), 13 C cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy ( 13 C{ 1 H}CP-MAS NMR), including the measurement of proton spinelattice relaxation time in t…
Influence of the modification, induced by zirconia nanoparticles, on the structure and properties of polycarbonate
2013
Melt compounding was used to prepare polycarbonate (PC)–zirconia nanocomposites with different amounts of zirconia. The effect of the zirconia loading, in the range of 1–5 wt.%, on the structure, mechanical properties and thermal degradation kinetics was investigated. The zirconia nanoparticle aggregates were well dispersed in the PC matrix and induced the appearance of a local lamellar order in the polycarbonate as inferred by SAXS findings. This order could be a consequence of the intermolecular interactions between zirconia and the polymer, in particular with the quaternary carbon bonded to the methyl groups and the methyl carbon as inferred from the NMR results. The presence of zirconia…
Macro-micro relationship in nanostructured functional composites
2012
This paper examines the results of the characterization of two functional composites: Poly(methyl methacrylate) (PMMA)-Ce:YAG (yttrium aluminium garnet doped with cerium) and PMMA-cobalt hexacyanoferrate (CoHCF). The composites were prepared as possible emitters in the fields of lighting thermal sensors. The prepared composites were char- acterized using transmission electron microscopy (TEM), nuclear magnetic resonance (NMR) spectroscopy, thermogravi- metric analysis (TGA), differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) analyses to study the correlation between micro and macro characteristics. We found that the molecular interactions of the two different fill…